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Icing impairs operation of helicopters, aircraft,
antenna, wind turbine, power and communication lines, ships,
superstructures, canal locks, etc. The coating that prevent icing or
facilitate ice removal attracts worldwide research.
We now have breakthrough on anti-icing coating and
formulated Miracle® AntiIce®
series anti-icing coating products. It is based on very low surface
energy, super water repellent, fluorinated silsesquoxane polymer with
flexible surfaces in micron scale. Ice cannot bond to Anti-Icing Coating®
coated surfaces. Miracle® AntiIce®
coated surfaces will keep zero ice adhesion until coatings are severely
contaminated or damaged. It is specially suitable for automobile
windshield glass and ships for cold areas.
Low ice adhesion coating has been the worldwide interest
of research fields. NASA Lewis has performed icing research for over 6o
years, operating the world's largest refrigerated icing tunnel, the
Icing Research Tunnel (IRT). The airspeeds up to 160m/s (350 mph), low
temperature to -30กใ C (-20กใ
F), water spray droplets 15-40 micron with content of 0.2-3.4 g/m3 are
for ice impact ice tests. During 60 years period numerous requests have
been received from organizations ranging from in size from individual
inventors to large corporations to test ice-phobic coatings for prevent
ice from adhering to aircraft surfaces. Many large corporations, such as
DuPont, PPG, Dow Chemicals, and BFGoodrich Aerospace maintain the
interest in the development of low ice-adhesion coatings.
Fluonova, Inc. (previous Elastic Ceramic Coatings, ECC) have involved in
low-ice-adhesion coatings and had provided 12 different material samples
tested in NASA IRT and had 2 types with lowest ice adhesion
records.** By understanding the material structure-ice adhesion
relation. Fluonova Inc. has improved its materials on low ice-adhesion
coatings. Now we are provide Miracle®
AntiIce® coating with 1K coating and
2K aerosol formulations. It is transparent and adhering to glass or 2k
fluorinated polyurethane paint, but cannot directly bond to metal surfaces. Miracle® AntiIce®
is especially good for automobile windshield application. Performance of
ice repellence are excellent on clean glass, 2k fluorinated polyurethane
coated metals. However, AntiIce® will not
work on any surface that is painted with waterborne paints. Since
waterborne paints have to have surfactants as ingredient making resin
dispersible in water. Because surfactants change surfaces from
hydrophobic to hydrophilic, therefore, bonds ice strongly.
Ice is the best adhesive. Ice bonds to any surfaces if
it is a solid. Ice adhesion is results from surface hydrogen bonds with
water molecule. Van der Waals forces is a secondary force. Super-hydrophobic
surface made of fluoropolymers reduces ice adhesion due to high
percentage (>95%) of water-air contact area and low percentage (<5%) of
water-solid contact area which has low surface energy. The material
submicron-nanometer structures on low energy surfaces are very
important. In the nature, feathers of some birds shown the
superstructures with super-hydrophobicity. Birds' feathers have delicate
surface structures with super strong mechanical strength and elasticity.
Super-hydrophobic surfaces shown low-icing adhesion for low speed wind
such as under 50m/sec speed. High speed wind creates high impact on
surfaces. Icing under high speed creates impact ice. The occluded air
pocket under such water interface is under pressure. In such case, water
penetrates into void. When water freezes into ice, the volume expands.
If submicron-nanometer structures are rigid, repeated water-icing cycles
would remove such rigid structures. The efficiency of low icing
adhesion of superhydrophobic man made rigid super hydrophobic surfaces
dramatically eliminated with impact icing conditions.
Very important, low ice adhesion coating cannot resist environmental
contamination. For example, super hydrophobic surfaces, nature or man
made super-hydrophobic surfaces both loss hydrophobicity and changed to hydrophilic by contact with
surfactants.. Surfactants permanently destroy super hydrophobicity of
Lotus leave, feathers and many man made super-hydrophobic samples. Only
fluorinated polymer surfaces are recoverable after totally washed off
all surfactants.
** AIAA-97-0303: Tests of the Performance of Coatings
for Low Ice Adhesion, D. N. Anderson, NASA Lewis Research Center,
Cleveland, OH and A.D. Reich, BFGoodrich R&D Center, Brecksville, OH
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